多层介质膜脉宽压缩光栅清洗方法研究

采用SPM (Sulfuric-Peroxide Mixtures, 98wt%H₂SO₄+30wt%H₂O₂)+兆声(方法1)和氧等离子体+HPM (Hydrochloric/Peroxide Mixture, 37wt%HCl+30wt%H₂O₂+DIH₂O)+兆声(方法2)两种清洗方法对多层介质膜脉宽压缩光栅进行清洗, 并对清洗前后样品的表面元素含量、衍射效率、表面粗糙度、表面温升以及激光损伤阈值等参数进行测量以评估两种清洗方法清洗效果。在入射角70°, 脉宽12 ns, s偏振, 波长1064 nm的激光辐照下, 经过清洗方法1清洗后的光栅样品单脉冲激光损伤阈值为7.55 J/cm ², 而方法2清洗后的样品损伤阈值为5.32 J/cm ²。另外, 虽然经过方法2清洗后样品表面杂质含量更低, 但是在衍射效率、表面粗糙度和表面温升都劣于经方法1清洗后的样品, 进一步分析发现方法2中氧等离子体清洗过程引入的Fe元素影响了其样品损伤性能和温升性能。因此, SPM清洗方法可以作为多层介质膜脉宽压缩光栅提升抗激光损伤性能的优化清洗方案。     

Study of MW-scale biogas-fed SOFC-WGS-TSA-PEMFC hybrid power technology as distributed energy system: Thermodynamic,exergetic and thermo-economic evaluation

Advanced biogas power generation technology has been attracting attentions, which contributes to the waste disposal and the mitigation of greenhouse gas emissions. This work proposes and models a novel biogas-fed hybrid power generation system consisting of solid oxide fuel cell, water gas shift reaction, thermal swing adsorption and proton exchange membrane fuel cell (SOFC-WGS-TSA-PEMFC). The thermodynamic, exergetic, and thermo-economic analyses of this hybrid system for power generation were conducted to comprehensively evaluate its performance. It was found that the novel biogas-fed hybrid system has a gross energy conversion efficiency of 68.63% and exergy efficiency of 65.36%, indicating high efficiency for this kind of hybrid power technology. The market sensitivity analysis showed that the hybrid system also has a low sensitivity to market price fluctuation. Under the current subsidy level for the distributed biogas power plant, the levelized cost of energy can be lowered to 0.02942 $/kWh for a 1 MW scale system. Accordingly, the payback period and annual return on investment can reach 1.4 year and about 20%, respectively. These results reveal that the proposed hybrid system is promising and economically feasible as a distributed power plant, especially for the small power scale (no more than 2 MW).     

论张位《词林典故》修撰的原因及意义

作为"词林"的翰林院在明代被目为仕途要津,翰林官的行为规范因之备受朝野瞩目.《词林典故》由翰林学士张位、于慎行等人在万历十四年(1586)编成并刊行.该书将明代翰林官的公务活动分为33类,不仅是明代翰林官的行为规范手册,也是明代万历时期官修典制的典范,起到了以"典故"形式约束翰林官言行的作用.从史学史的角度考量,该书还是明代中后期修史热潮中的产物,发挥了保存国故的重要作用.     

基于Kӧtter方程的盾构掘进面上被切削土体受力研究

为了计算不同土体性质与不同掘进参数下盾构刮刀与土体之间的作用力以及由此带来的切削扭矩,引入了修正后的Kӧtter方程作为补充方程,求解出开挖面上土体在被动切削至破坏时滑动面上的应力分布,建立了被切削土体受力模型,求解出刮刀刃面与土体之间的正压力p、摩擦力Q与侧向土体间抗剪阻力U,进而推导出刀盘切削扭矩T的计算公式。分析得到特定刀盘上刮刀的p,Q,U值随土体c,φ值增大而增大,通过适当提高刮刀刃面粗糙度来增大摩擦可使土体更易被切至破坏;p,Q,U值随刀盘转速ω增大而减小,p,Q随支护荷载p线性增大且p对于被切削土体受力的影响在砂性土中较大,最终给出特定刀盘掘进至部分种类土体中的切削扭矩值作为工程参考。     

基于变量决策层的启发式变量选择策略

启发式分支策略是SAT求解器中不可或缺的一部分，直接影响求解器的效率。早期的启发式分支决策需要遍历整个子句数据库，效率比较低。随着独立变量状态衰减和（Variable State Independent Decaying Sum, VSIDS）分支策略的出现，SAT求解器的效率有所提高，但VSIDS策略以及它的延伸策略中变量的增量都只是与变量的冲突次数有关，没有考虑变量的决策层在分支策略中的影响。因此当发生冲突时，如果与冲突有关的变量的得分相同而决策层不同时，对于变量的选择就具有随机性。基于此，本文在阐述变量的决策层的重要性之后在VSIDS策略的基础上，提出一种基于变量决策层的启发式变量选择策略--HSVDL策略。然后通过实例显示HSVDL策略在变量决策阶段选择决策层低的变量的可能性比选择决策层高的变量的可能性要大，而且得分比较小，减少了内存的占用。最后通过实验表明HSVDL策略能够求解出更多的实例，求解器的效率也有所提高，说明该策略有一定的优势。     

Ductile-brittle transition mechanisms of amorphous glass subjected to taper grinding experiment

Taper grinding experiments were conducted in this paper to investigate the continuous and complete ductile-brittle transition process of two kinds of amorphous glass: high purity fused silica (HPFS) which is silica rich glass and soda-lime silica glass (SLSG) which is low silica glass. The grinding force, ground surface morphology, surface roughness, and subsurface damage depth induced during different stages of taper grinding were all analyzed. A mathematical model describing the cutting force of a grit and micro-crack length was established to clarify the ductile-brittle transition mechanisms of isotropic material. The model revealed that material removal mechanisms and grinding force were mainly determined by the crack equivalent length in front of the grit and its equivalent cutting force. The ground surface roughness and subsurface damage depth were mainly affected by the cutting force of the grit and length of cracks behind it. The ductile machinability of SLSG was better than that of HPFS due to the bonding of metallic atoms in SLSG with nonbridging oxygens, as well as their packing into free volume in SiO₂ network.     

Structural,optical and electrical properties of indium doped Cu2ZnSn(S,Se)4 thin films synthesized by the DC and RF reactive magnetron cosputtering

Element doping into the Cu₂ZnSn(S,Se)₄ (CZTSSe) absorber is an effective method to optimize the performance of thin film solar cells. In this study, the Cu₂In_xZn_1-xSn(S,Se)₄ (CIZTSSe) precursor film was deposited by magnetron cosputtering technique using indium (In) and quaternary Cu₂ZnSnS₄ (CZTS) as targets. Meanwhile, the In content was controlled using the direct current (DC) power on In target (P_In). A single kesterite CIZTSSe alloy was formed by successfully doping a small number of In³⁺ into the main lattice of CZTSSe. The partial Zn²⁺ cations were substituted by In³⁺ ions, resulting in improving properties of CZTSSe films. Morphological analysis showed that large grain CIZTSSe films could be obtained by doping In. The well-distributed, smooth, and dense film was obtained when the P_In was 30 W. The band gap of CIZTSSe could be continuously adjusted from 1.27 to 1.05 eV as P_In increased from 0 to 40 W. In addition, the CIZTSSe alloy thin film at P_In = 30 W exhibited the best p-type conductivity with Hall mobility of 6.87 cm²V^?1s^?1, which is a potential material as the absorption layer of high-performance solar cells.     

A new As3Mo8V4/PANi/rGO composite for high performance supercapacitor electrode

Herein, [As₂^IIIAs^VMo₈^VIV₄^IVO₄₀]₂[Cu^ICu₂^II(pz)₄]₂·9H₂O/polyaniline/reduced graphene oxide (pz = pyrazine, abbreviated to As₃Mo₈V₄/PANi/rGO) composite is first assembled, characterized and systematically explored for its supercapacitor performance. As₃Mo₈V₄/PANi/rGO composite shows a exceptional specific capacitance (2351 F g^?1 at 1 A g^?1) and outstanding cyclic stability (96.9% after 5000 cycles). The symmetric supercapacitor exhibits high specific capacitance of 1295 F g^?1 at 1 A g^?1 and excellent energy density of 88.1 Wh kg^-1 at power density of 349.6 W kg^-1, while maintaining a notable capacitance retention of 85.7% after 5000 cycles at 2 A g^-1. The above results confirm the potential application of As₃Mo₈V₄/PANi/rGO composite in energy storage devices.     

煤磨热风管线旋风收尘器的改造

对5?000 t/d生产线煤磨热风管线收尘器进行改造，拆除原双旋风收尘器，利用原框架，缩小旋风筒直径与高度比例，提高旋风筒高度，缩小内筒直径尺寸，来提高收尘效率。改造后入窑煤粉灰分5?000 t/d线与2?000 t/d线差异减小到0.05%，相对降低了1.17%。     

基于区间犹豫模糊语言集的水资源多目标决策

以鄂北水资源配置工程为对象,研究大型调水工程背景下的多水源多目标优化配置。将鄂北地区水库分为充蓄水库、补偿水库与在线水库等3类,根据各类水库特点对鄂北水资源配置工程进行系统概化,建立以年缺水量最小和调水成本最低为目标函数的多水源多目标优化配置模型。采用权重系数法进行求解得到非劣解集。最后采用基于区间犹豫模糊语言与TOPSIS的多目标决策方法对各方案的缺水量与调水量作出评价并遴选出最优方案。研究结果表明:对鄂北水资源配置工程而言,缺水量与调水量的权重比为7∶3的方案综合评价最优,重视缺水的同时兼顾调水成本;基于区间犹豫模糊语言集与TOPSIS的水资源多目标决策方法经本文实例验证具有较高的稳定性与可行性。